Laboratory for Molecular Photonics
Department of Chemistry
University of Miami
Goal: The goal of this project was the identification of strategies to assemble films of electroactive building blocks on transparent metallic electrodes in a single and efficient experimental step.
Results: The Laboratory of Molecular Photonics developed electrochromic multilayers of bipyridinium dications able to self-
Keywords: Bipyridinium Dications Electrochromism Electron Transport Monolayers Multilayers Self-
"Electroactive Films of Multicomponent Building Blocks": I. Yildiz, J. Mukherjee, M. Tomasulo, F. M. Raymo, Adv. Funct. Mater., 2007, 17, 814–820
"Electroactive Films Incorporating 4,4'-
"Electron Transport in Bipyridinium Films": F. M. Raymo, R. J. Alvarado, Chem. Rec., 2004, 4, 204–218
The electrochemical reduction and back oxidation of bipyridinium dications, embedded within multilayer assemblies adsorbed on transparent metallic electrodes, modulates the absorbance of the overall material.
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